|
|
4-nitrobenzoate + CoA + ATP <=> 4-nitrobenzoyl-CoA + AMP + diphosphate
|
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.33
4-chlorobenzoate---CoA ligase
6.2.1.M32
|
–
–
–
|
| |
BRENDA:
BS324
MetaCyc:
RXN-20207
|
|
|
|
(2Z,4Z,8E,10E,12E,14E)-3,5-dihydroxy-2,4,8,10,12,14-hexamethyl-15-(4-nitrophenyl)pentadeca-2,4,8,10,12,14-hexaenoyl-[spectinabilin_polyketide_synthase] <=> demethyldeoxyspectinabilin + holo-[spectinabilin_polyketide_synthase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20236
|
|
|
|
4-Aminobenzoic_acid + O2 + reduced_acceptor <=> 4-nitrobenzoate + H2O + acceptor
|
1.14.99.ag
|
–
|
| |
MetaCyc:
RXN-20202
|
|
|
|
S-adenosyl-L-methionine + demethyldeoxyspectinabilin <=> S-adenosyl-L-homocysteine + deoxyneoaureothin + H+
|
2.1.1.353
demethylluteothin O-methyltransferase
|
–
|
| |
MetaCyc:
RXN-20237
|
|
|
|
deoxyneoaureothin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> neoaureothin + H2O + oxidized_ferredoxin
|
1.14.15.37
luteothin monooxygenase
|
–
|
| |
BRENDA:
BS447405
MetaCyc:
RXN-20238
|
|
|
|
holo-[spectinabilin_polyketide_synthase] + 4-nitrobenzoyl-CoA + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> (2Z,4Z,8E,10E,12E,14E)-3,5-dihydroxy-2,4,8,10,12,14-hexamethyl-15-(4-nitrophenyl)pentadeca-2,4,8,10,12,14-hexaenoyl-[spectinabilin_polyketide_synthase] + CO2 + CoA + NADP+ + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20234
|
|
